In the Piccolo Jr.
Because right before fighting her he says "Well I'm up next. I'm feeling really cheerful for native tits reason! Cutey's your opponent!
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Then when they finally are engaged and Chi Chi clings on to him you see Goku blush for the first time in the entire dragonball series. Which again, could be attributed to embarrassment or the fact that he likes her. So do you guys think he likes Chi Chi at all when he decides to marry her?
And by "like" I mean in a romantic manner. And I know in the dubbed version Goku says "but I know what my heart wants" or something to that effect, but that was funimation creating their own lines.
In the subbed version he never says that.